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Triaminoguanidine is a kind of non-azide nitrogen-rich flammable compound, which has some advantages of high nitrogen, good thermal stability, and high positive formation enthalpy, etc.

氨基胍是一种非叠氮类、富氮型、可燃化合,其系列含能化合具有高的正生成、热稳、氮含量高等特点。

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So, the formula for enthalpy is usually written as change in enthalpy.

因此,焓公式通常写焓变。

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It's analogous to the standard enthalpy of formation that we use to calculate change in enthalpy.

它类似于我们用来计算焓变焓。

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The law itself says nothing about the standard enthalpy of formation.

该定律本身并未提及标

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Change in enthalpy is equal to the heat gained or lost by the system.

变等于系统获得或损失热量。

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Like enthalpy and entropy, we can't directly the free energy change of the whole reaction.

和熵一样, 我们不能直接表示整个反应自由能变化。

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So I guess in the capital H for enthalpy does kinda make sense.

所以我在大写 H 中表示确实有点道理。

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Why enthalpy change is different from heat, even though they turn out to be pretty much the same anyway.

为什么变与热不, 尽管事实证明它们几乎是一样

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Like enthalpy or entropy, Gibbs free energy is a state function, so it can be calculated the same way.

或熵一样, 吉布斯自由能是一个状态函数, 因此可以用方式计算。

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Well no, because you don't even know why enthalpy is so cool.

嗯,不,因为你甚至不知道为什么这么酷。

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And we measure enthalpy with a weird little science called calorimetry.

我们用一种叫做量热法奇怪小科学来测量

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Those bonds are nothing but energy, and using enthalpy, we can measure how much energy they have.

这些键只不过是能量, 使用我们可以测量它们有多少能量。

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These measurements are done at standard conditions, which we discussed in the enthalpy and entropy episodes.

这些测量是在标条件下完, 我们在和熵情节中对此进行了讨论。

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So, I wonder how that compares to the amount we would predict using Hess's Law and the standard enthalpy of formation?

所以,我知道这与我们使用赫斯定律和标预测比如何?

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Hess' Law is often stated in terms of standard enthalpies of formation.

赫斯定律通常用标来表述。

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As long as you start with the same reactants and end with the same products, the enthalpy change is the same.

只要您从反应物开始并以产物结束, 变就

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Thanks to many hardworking chemists, the standard enthalpy of formation has been measured for hundreds of compounds.

感谢许多辛勤工作化学家,已经测量了数百种化合物

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And I'm very happy the inventors knew how to calculate the enthalpy change of chemical reactions.

我很高兴发明者知道如何计算化学反应变。

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Hopefully that sounds like fun because more about the ins and outs of this are coming in an episode on how to measure enthalpy.

希望这听起来很有趣,因为有关如何测量一集中将详细介绍这方面来龙去脉

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A large change in enthalpy can determine the direction of a free energy change, even if the entropy changes in the opposite direction, and vice versa.

大变化可以决定自由能变化方向,即使熵变化方向反, 反之亦然。

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Note that the standard enthalpy is in kilojoules while the standard entropy is in joules per Kelvin.

请注意,标单位是千焦耳, 而标单位是焦耳每开尔文。

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